To attach or to detach an existing content database use the below power shell command
Mount-SPContentDatabase "<ContentDb>" –DatabaseServer "<DbServer>" –WebApplication http://your WebapplicationName
Where
<ContentDb>: is the content database to be attached.
<DbServer> : is the name of the database server.
http://your WebapplicationName :is the name of the Web application to which the content database is being attached.
To detach a content database use the below power shell command
Dismount-SPContentDatabase "<ContentdBName>"
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