I'm a new C# learner, any advise tips on what to focus on first and what is the best way to learn it?

Do you have any programming background?
Start here:  http://www.c-sharpcorner.com/Beginners/   

This page has download links for Visual C# express and free books!

Good luck!

Oh and don't worry that book being about 3.0 NET. Its still a good book.

I am new at learning C sharp. Post on this forums and we will be glad to help you with the questions you will have through your learning process.
As for the books:
"A book I often recommend for beginners learning the C# language is this one by Herb Schildt which, as well as being a very good book for that purpose, is also one of the few books which contains some questions and answers:

http://www.amazon.com/3-0-Beginners-Guide-Herbert-Schildt/dp/0071588302/ref=dp_ob_title_bk  "- Vulpes

That book should be more than enough for the beginner, you can get it for free, just look for it, like i did~