Im starting my career as as .Net Developer

As you want to start your career in .Net, I am not sure whether you want to make career in Web or Desktop application.

 

Before we go deeply to Web and Desktop you need to learn basics

.Net Framework basics like FCL, CLS, architecture

C#/VB (http://www.c-sharpcorner.com/UploadFile/mahesh/best-C-Sharp-book/)

SQL SERVER(any other database but .Net mostly prefer SQL Server)

 

There are many technologies are available for Web application. These are:

 

ASP.NET webforms

MVC

AZURE Cloud Services

Sharepoint

MS CRM Dynamics 

WCF web service  

 

Choose one them which is you are more interested and work on it. Every technology has its advantages and disadvantages, so don't confuse. Choose as per area of interest like for Cloud technology you can go Azure. It is better you should start with either ASP.NET web form or MVC. Then you can work on other technology because here you get some confidence, basic idea.

 

Still you must have knowledge on other web technology to become a complete web developer.

 

HTML, Javascript, jQuery, CSS -  W3 schools best site for beginners.

 

In desktop application, WPF is most demanding part. If you are interested go for that.

 

To learn above you can go for any nearby good .Net institute or if you want learn self then so many online tutorials are there, you ca use that. Which is suitable for you go for that but do always practice by writing demo programs that will give confidence.

 

Always learn and do practice... 

First you learn basic of dot net later you start first Asp.net ,C# , Ado.Net then you go for more framework and technology ,