need to learn wcf and wpf

Plan this way . Learn basic of wcf address , binding contract Understand data contract, message contract , operation contract. Develop a sample service and consume it from a asp.net pageUnderstand different type of binding ( basic http binding and wshttp binding Is enough for you now)Understand data contract , data contract serialization etcLearn what is a wcf rest service ( now it is used widely)Learn different attribute data contract and it's members. Create a Web form and call the wcf from the Web page by creating proxy.Understand different way of communication simplex duplex one way call.Learn how to implement security in wcf . Many authors have written lot of article .Please learn this and do as much as hands on . Hope this helps .

Start learning from c-sharp corner . They are very simple , easy to understand .