There are 3 main difference.
1. The namespaces
OrderedDictionary => System.Collections.Specialized;
SortedDictionary => System.Collections.Generic;
2. In SortedDictionary key/pair is sorted by key but not in OrderedDictionary.
3. In OrderedDictionary values can access either with key or index. In SortedDictionary values are only access through key.