Bind Dropdownlist using Enterpriselibrary 5.0.
Your aspx page like
<%@
Page Language="C#"
AutoEventWireup="true"
CodeFile="Default.aspx.cs"
Inherits="_Default"
%>
<!DOCTYPE
html PUBLIC
"-//W3C//DTD XHTML 1.0 Transitional//EN" 
"http://www.w3.org/TR/xhtml1/DTD/xhtml1-transitional.dtd">
<html
xmlns="http://www.w3.org/1999/xhtml">
<head
runat="server">
    <title></title>
</head>
<body>
   
<form
id="form1"
runat="server">
    <div>
      City:  <asp:DropDownList
ID="ddl_city"
runat="server">
        </asp:DropDownList>
    </div>
    </form>
</body>
</html>
Your .cs file like
using 
System;
using 
System.Collections.Generic;
using 
System.Linq;
using System.Web;
using 
System.Web.UI;
using 
System.Web.UI.WebControls;
using 
System.Data;
using 
System.Data.Common;
using 
System.Data.SqlClient;
using 
System.Configuration;
using 
Microsoft.Practices.EnterpriseLibrary.Common;
using 
Microsoft.Practices.EnterpriseLibrary.Data;
using 
Microsoft.Practices.EnterpriseLibrary.Data.Sql;
public
partial class
_Default : System.Web.UI.Page
{
    private string 
Connectionstring = ConfigurationManager.ConnectionStrings["connection"].ToString();
    protected void 
Page_Load(object sender,
EventArgs e)
    {
        if (!IsPostBack)
        {
            BindCityDropdownlist();
        }
    }
    
private void BindCityDropdownlist()
    {
        DataSet ds = 
new DataSet();
        Database objDB =
new SqlDatabase(this.Connectionstring);
        string SPName =
"Get_CityStateAreaInqSrc";
       
using (DbCommand 
objCMD = objDB.GetStoredProcCommand(SPName))
        {
            objDB.AddInParameter(objCMD, "@Action",
DbType.Int64, 2);
            try
            {
                ds = objDB.ExecuteDataSet(objCMD);
            }
            catch (Exception 
ex)
            {
                EventLog objLOG =
new EventLog();
                objLOG.LogError(ex);
                throw ex;
            }
        }
       
if (ds != null 
&& ds.Tables[0].Rows.Count > 0)
        {
            ddl_city.DataSource = ds.Tables[0];
            ddl_city.DataTextField = "Name";
            ddl_city.DataValueField = "Code";
            ddl_city.DataBind();
        }
    }
}