What should I learn first and next?

As a fairly new c# developer I've often wondered about what techologies I need or should strive to learn first.

I found a PowerPoint slide from last year that mentioned the following as being essential skills for a "ASP.NET Developer":

Dot Net Basics

SQL Server

ASP.NET

ADO.NET

GridView

Visual Studio

and nice to have skills:

Web Services

WCF

ASP.NET MVC

Entity Framework

LINQ

LINQ to XML

LINQ to SQL

and JQuery is also a nice to have skill.

I know a lot of these a good skills to have in general but I cannot find any guide/list of technologies that would be great to have before continueing to a more difficult subject.